New Way to Recycle Lithium-Ion Batteries

July 20th, 2018

Cobalt has been a very well known choke-point in lithium based energy storage systems for many years. Tesla, for example, has been reducing its dependence on cobalt and will go cobalt free for its next generation of cells. Although, what that means, in terms of an ETA, isn’t clear. The point is that the largest manufacturer of lithium ion batteries in the world is phasing out the use of cobalt entirely.

My guess is that other companies are looking at alternatives as well.

Via: Los Angeles Times:

The promise of a global electric-vehicle transformation has a looming problem.

The cathodes in the lithium-ion batteries typically used in electric vehicles are made of metal oxides that contain cobalt, a metal found in finite supplies and concentrated in one of the globe’s more precarious countries.

But an assistant professor at UC San Diego says he has developed a way to recycle used cathodes from spent lithium-ion batteries and restore to perform as well as they did when new.

“Yes, it can work effectively,” said Zheng Chen, a 31-year-old who works as a nanoengineer at the Sustainable Power and Energy Center at UC San Diego’s Jacobs School of Engineering.

The method also works on lithium cobalt oxide, which is widely used in electronic devices such as smartphones and laptops.

The process takes degraded particles from the cathodes found in a used lithium-ion battery. The particles are then pressurized in a hot alkaline solution that contains lithium salt. Later, the particles go through a short heat-treating process called annealing, in which temperatures reach more than 1,400 degrees Fahrenheit.

After cooling, Chen’s team takes the regenerated particles and makes new cathodes. They then test the cathodes in batteries made in the lab.

The results, Chen said, have been impressive.

The new cathodes have been able to maintain the same charging time, storage capacity and battery lifetime as the originals did.

“Originally I thought we couldn’t get all this performance back, that we would lose 10% or 20%,” Chen said. “But it turns out we’re getting exactly the same performance.”

Details of the recycling method were recently published in the research journal Green Chemistry, submitted by Chen and two colleagues.

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